Cyanogen formation during asymmetric cyanohydrin synthesis.
نویسندگان
چکیده
During asymmetric cyanohydrin synthesis catalysed by vanadium(V)oxo(salen) complexes, the catalysts are reduced to vanadium(IV)oxo(salen) as determined by EPR spectroscopy; the reducing agent is cyanide which is oxidised to cyanogen via a non-radical mechanism.
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ورودعنوان ژورنال:
- Chemical communications
دوره 46 19 شماره
صفحات -
تاریخ انتشار 2010